Carbocation rearrangements may give products where there is change in ring size. An example is shown below:
Fig. 1: A carbocation rearrangement with ring change is shown. The rearrangement gives a more stable tertiary carbocation |
Another example of carbocation rearrangement and ring change (ring expansion) is shown in Fig. 2. The reaction is a pinacol rearrangement and in this case leads to ring expansion.
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